湖南6种母质发育水稻土对镉和砷的吸附和解吸特征
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农业农村部与财政部科研专项(NBCH2016–6)


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    摘要:

    以湖南省典型母质发育的鳝泥田、红泥田、河砂泥田、麻砂泥田、酸紫砂泥田和灰泥田等6种水稻土为研究对象,采用单元素一次平衡法研究土壤对镉、砷的吸附与解吸特性及其影响因素。结果表明:供试水稻土对镉、砷的等温吸附曲线均呈非线性;供试土壤吸附平衡时,溶液中镉或砷的浓度与土壤对镉或砷的吸附量关系用Langmuir、Freundlich和Temkin等3种模型拟合均达显著水平,决定系数(R2)为0.842~0.994,其中以Langmuir方程的拟合(R2均值0.964)更优,但不同水稻土不同元素的最优方程有所差异,灰泥田的镉和酸紫砂泥田的砷用Temkin方程的拟合度较高,鳝泥田、红泥田和河砂泥田的砷用Freundlich方程的拟合度较高;土壤对镉的吸附量大于对砷的吸附量;以Langmuir方程拟合所得不同水稻土镉、砷最大吸附量(Xm)比较,整体上镉以灰泥田的(1379.9 mg/kg)最大,酸紫砂泥田的(527.8 mg/kg)最小;砷以红泥田的(587.4 mg/kg)最大,灰泥田的(266.6 mg/kg)最小;土壤镉、砷解吸量随镉、砷吸附量增大呈曲线向上弯曲增长;土壤镉、砷解吸率分别为23.2%~93.8%和0.5%~44.2%,镉解吸率以酸紫砂泥田的最高(均值83.9%),灰泥田的最低(均值43.7%),砷解吸率以酸紫砂泥田的最高(均值20.3%),红泥田的最低(均值7.2%);相关性分析表明,土壤pH值和游离氧化铁含量分别是影响土壤对镉、砷的最大吸附量及平均解吸率的主要因子;6种母质水稻土中,灰泥田镉的吸附分配系数(Kd)和保留因子(K0)(5.86~ 11 557.25、0.08~387.37 L/kg)最大,酸紫砂泥田的(1.89~2765.17、0.02~47.31 L/kg)最小;红泥田砷的Kd和K0(6.17~406.29、0.31~770.85 L/kg)最大,酸紫砂泥田的(2.34~22.51,0.05~3.50 L/kg)最小。

    Abstract:

    The adsorption and desorption characteristics and influencing factors of cadmium and arsenic were investigated in paddy soils derived from six typical parent materials from Hunan, using single element equilibrium method. The studied six materials were eel clayey soil, red clayey soil, alluvial sandy soil, granitic sandy soil, sour purple sandy soil and grey clayey soil. The results showed that the isothermal adsorption curves of cadmium and arsenic in paddy soil were nonlinear. The relationship between the concentration of cadmium or arsenic in the solution and the adsorption amount of cadmium or arsenic in the soil was significantly fitted by Langmuir, Freundlich and Temkin models, and the determination coefficient(R2) was 0.842-0.994. Among them, the fitting of Langmuir equation(R2 mean value 0.964) was better, but the optimal equations of different elements in different paddy soils were different. The cadmium in the grey clayey soil and the arsenic in the sour purple sandy soil were better fitted by the Temkin equation. The arsenic in the eel clayey soil, red clayey soil and alluvial sandy soil were better fitted by the Freundlich equation. The adsorption capacity of cadmium in soil was greater than that of arsenic. The Langmuir fitting equation showed that the maximum adsorption capacity(Xm) of cadmium in different paddy soils was the highest in the grey clayey soil(1379.9 mg/kg) and the lowest in the sour purple sandy soil(527.8 mg/kg); and that of the arsenic in red clayey soil(587.4 mg/kg) was the largest and that in grey clayey soil(266.6 mg/kg) was the smallest. The desorption amounts of cadmium and arsenic in soil increased with the increase of the adsorption amounts of cadmium and arsenic. The desorption rates of cadmium and arsenic were 23.2%-93.8% and 0.5%-44.2%, respectively. The cadmium desorption rate of sour purple sandy soil was the highest(mean 83.9%), while that of grey clayey soil was lowest(mean 43.7%); and the arsenic desorption rate of sour purple sandy soil was the highest(mean 20.3%), while that of red clayey soil was lowest(mean 7.2%). Correlation analysis showed that soil pH value and free ferric oxide content were the main factors affecting the maximum adsorption capacities and average desorption rates of cadmium and arsenic, respectively. Among the six parent paddy soils, the partition coefficients(Kd) and retention factors(K0) of Cd were the highest in the grey clayey soil(5.86-11 557.25, 0.08-387.37 L/kg), and the lowest in the sour purple sandy soil(1.89-2765.17, 0.02-47.31 L/kg). The Kd and K0 of arsenic in red clayey soil (6.17-406.29, 0.31-770.85 L/kg) were the highest, and the lowest in sour purple sandy soil(2.34-22.51, 0.05-3.50 L/kg).

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曾莹,王翠红,李富升,郑晴文,康霞,许毅隽.湖南6种母质发育水稻土对镉和砷的吸附和解吸特征[J].湖南农业大学学报:自然科学版,2023,49(2):.

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  • 在线发布日期: 2023-05-04
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