肟菌酯及其代谢产物在苹果中的残留与膳食风险评估
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湖南省教育厅优秀青年基金项目(20B304);绿色农药与农业生物工程教育部重点实验室开放基金课题(黔教合KY字[2019]036)


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    摘要:

    在中国苹果主产区山东青岛、宁夏银川、辽宁大连等12地进行肟菌酯在苹果中的规范残留试验。苹果样品中肟菌酯及其代谢产物CGA321113(肟菌酸)的残留量采用乙腈提取,经抽滤、盐析、浓缩后用乙酸乙酯定容,再运用气相色谱检测,并对肟菌酯进行膳食风险评估。结果表明:在添加水平为0.05、0.50、5.00 mg/kg时,肟菌酯和CGA321113在苹果中的平均添加回收率分别为89%~99%和89%~98%,相对标准偏差分别为6%~10%和7%,定量限均为0.05 mg/kg;以肟菌酯有效成分100 mg/kg的用量在苹果上施药3次,每次施药间隔7 d,在末次施药后28 d时,肟菌酯在苹果中的残留量为<0.05~0.14 mg/kg,CGA321113的残留量为<0.05~0.06 mg/kg,肟菌酯的残留总量为<0.10~0.19 mg/kg;在末次施药后21 d时,肟菌酯在苹果中的残留量为<0.05~0.15 mg/kg,CGA321113的残留量为<0.05~0.28 mg/kg,肟菌酯的残留总量为<0.10~0.37 mg/kg,残留总量最大值低于中国制定的肟菌酯在苹果中的最大残留限量值;肟菌酯的国家估算每日摄入量为0.19 mg,风险商为7.5%,表明肟菌酯膳食摄入风险处于可接受水平。

    Abstract:

    The supervised field trials of trifloxystrobin in apples was carried out in the 12 main apple producing areas in China, including Qingdao of Shandong, Yinchuan of Ningxia and Dalian of Liaoning, etc. The residues of trifloxystrobin and its metabolite CGA321113(trifloxystrobin acid) in the collected apple samples were extracted with acetonitrile, fixed volume with ethyl acetate after suction filtration, salting out and concentration, and then detected by gas chromatography. The dietary risk of trifloxystrobin was evaluated. The results showed at the additional levels of 0.05, 0.50 and 5.00 mg/kg, the average recoveries for trifloxystrobin and CGA321113 in the apples were 89%-99% and 89%-98% with relative standard deviation were 6%-10% and 7%, respectively. The limit of quantitation both were 0.05 mg/kg. The trifloxystrobin was sprayed on apples for 3 times with an effective component of 100 mg/kg, and the spraying interval was 7 d. At 28th day after the last pesticide application, the residue of trifloxystrobin in apples were <0.05-0.14 mg/kg, the residue of CGA321113 were <0.05-0.06 mg/kg, and the total residue of trifloxystrobin in apple were <0.10-0.19 mg/kg. On the 21st day, the residue of trifloxystrobin in apples were <0.05-0.15 mg/kg, the residue of CGA321113 were <0.05-0.28 mg/kg, and the total residue of trifloxystrobin in apple were <0.10-0.37 mg/kg. The maximum total residue was lower than the maximum residue limit of trifloxystrobin in apple formulated by China. The national estimated daily intake of trifloxystrobin was 0.19 mg and the risk quotient was 7.5%. The risk assessment result showed that the dietary intake risk of trifloxystrobin was at an acceptable level.

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李文博,苏龙.肟菌酯及其代谢产物在苹果中的残留与膳食风险评估[J].湖南农业大学学报:自然科学版,2023,49(1):.

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  • 在线发布日期: 2023-03-03
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