二氯喹啉酸在几种矿物上的吸附特性及其机理
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湖南省研究生科研创新项目(CX2011B309);农业部农药残留试验项目(NYBNYCL20100057)


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    摘要:

    采用批量平衡振荡法,研究二氯喹啉酸在3种不同结构矿物中的吸附特性,并通过FTIR和XRD分析,探讨其吸附机理。结果表明:1) 二氯喹啉酸在3种供试矿物中的吸附动力学过程均包含了快速反应阶段和慢速平衡阶段,其吸附动力学曲线均符合准二级动力学方程、颗粒扩散方程和Elovich方程,其中以准二级动力学方程的拟合程度最好,在颗粒扩散方程中的常数项(c值)不为零,这表明颗粒内的扩散速率不是决定二氯喹啉酸在供试矿物中吸附快慢的唯一因素。2) 二氯喹啉酸在供试矿物中的吸附等温线均符合线性模型和Freundlich模型。3) FTIR分析表明,二氯喹啉酸通过氢键、电荷–偶极键、络合作用和电荷转移吸附在高岭石中,通过氢键、电荷–偶极键和络合作用吸附在沸石和海泡石中。4) XRD分析表明,二氯喹啉酸在海泡石中的吸附均发生在其表层,而未进入其内层,但在高岭石和沸石中的吸附不仅发生在其表层,而且还能进入其内层。

    Abstract:

    Batch equilibrium experiments were conducted to study the adsorption characteristics and mechanisms of quinclorac by three types of minerals with different composition. Methods of FTIR and XRD analysis were employed to explain the functional mechanism between quinclorac and minerals. The results showed that:1)The adsorption of quinclorac by three minerals were included in both rapid stage and slow equilibrium stage. The adsorption kinetics consisted with the pseudo-second-order equation, the particle diffusion equation, and Elovich equations, and among of them, fitting from the pseudo-second-order was the best. In addition, it was indicated that the speed of particle diffusion was not a sole factor judged from the nonzero constant c in the particle diffusion equation. 2)The isotherms of quinclorac adsorption by these minerals were well described by linear and Freundlich equation. 3)It was showed from FTIR analysis that adsorption of quinclorac by kaolinite was via hydrogen bond, charge dipolar bond, complexation, and charge transfer. While, the adsorption by zeolite and sepiolite was depend on H–bond, charge dipolar bond and complexation. 4) The analysis from XRD showed that the adsorption of quinclorac only occurred on the surface of sepiolite, and unreached its interlayer, while the adsorption by kaolinite and zeolite not only occurred on the surface but reached their interlayer.

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杨丽华,龚道新,周健,袁雅洁,陈宣宇,王寒.二氯喹啉酸在几种矿物上的吸附特性及其机理[J].湖南农业大学学报:自然科学版,2015,41(2):.

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  • 在线发布日期: 2015-03-30
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